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The motivation of the present work was to understand the mechanism by which alcohols produce less aromatic species in their combustion process than an equal amount of hydrocarbon with similar molecular structure does. Due to its numerous advantages over short-chain alcohols, butanol has been considered very promising in soot reduction. Excluding the influence of spray, vaporization and mixing process in engine cases, an adiabatic constant-pressure reactor model was applied to investigate the effect of butanol additives on aromatic species, which are known to be soot precursors, in fuel-rich butane flames. To keep the carbon flux constant, 5% and 10% oxygen by mass of the fuel were added to butane using butanol additive, respectively. Based on the soot reduction effects proposed in literature, effects on temperature, key radical concentrations and the carbon removal from the pathway to aromatic species were considered to identify the major mechanism of reduction in aromatic species.

The performance and emission of an AVL 5402 single-cylinder engine fueled with acetone-butanol-ethanol (ABE) / diesel blends were experimentally investigated at various load conditions and injection timings. The fuels tested in the experiments were ABE10 (10% ABE, 90% diesel), ABE20 and diesel as baseline. Thermodynamics analyses of pressure traces acquired in experiments were performed to show the impact of ABE concentration to the overall combustion characteristics of the fuel mixtures. Cumulative heat release analysis showed that ABE mixtures generally retarded the overall combustion phasing, ignition delays of ABE-containing fuels were significantly extended, however, combustion rate during CA10∼CA50 were accelerated at different extent. Pressure rise rate of ABE-containing fuels further implicated that the premixed combustion were more dominant than that of diesel. Polytropic indices of both expansion and compression strokes were calculated from p-V diagram.

This work presents a comprehensive computational study of diesel - natural gas (NG) dual fuel engine. A complete computational model is developed for the operation of a diesel - NG dual fuel engine modified from an AVL 5402 single cylinder diesel test engine. The model is based on the KIVA-3V program and includes customized sub-models. The model is validated against test cell measurements of both pure diesel and dual fuel operation. The effects of NG on ignition and combustion in dual fuel operation are analyzed in detail. Zero-dimensional computations with a diesel surrogate reaction mechanism are conducted to discover the effects of NG on ignition and combustion and to reveal the fundamental chemical mechanisms behind such effects. Backed by the detailed theoretical analysis, the engine operation parameters are optimized with genetic algorithm (GA) for the dual fuel operation of the modified AVL 5402 test engine.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

An experimental investigation was conducted using a Ford single-cylinder spark-ignition research engine to compare the performance and emissions of neat n-butanol fuel to that of gasoline and ethanol. Measurements of brake torque and exhaust gas temperature along with in-cylinder pressure traces were used to study the performance of the engine and measurements of emissions of unburned hydrocarbons, carbon monoxide, and nitrogen oxide ere used to compare the three fuels in terms of combustion byproducts. It was found that gasoline and butanol are closest in engine performance with butanol producing slightly less brake torque. Exhaust gas temperature and nitrogen oxide measurements show that butanol combusts at a lower peak temperature. Of particular interest were the emissions of unburned hydrocarbons which were between two and three times those of gasoline suggesting that butanol is not atomizing as effectively as gasoline and ethanol.

Performance and emissions of a common-rail production diesel engine fueled with soybean-derived biodiesel was investigated. The work was broken down into two categories. First, adjustment of injection timing and EGR ratio was investigated as a means to reduce NOx emissions to levels comparable with those obtained when using pure diesel fuel. Next, simultaneous reduction of NOx and soot emissions was investigated using high rates of EGR combined with late injection timings to approach the low-temperature combustion regime. Results from the first part of the study indicate that optimization of engine control parameters for use with biodiesel can be beneficial to performance and emissions. It was found that adjusting the engine's MAF setpoint table to reflect the difference in stoichiometric air-fuel ratio between diesel and biodiesel brought NOx emissions to comparable or lower levels.

Ternary blends of butanol-biodiesel-diesel with different blending ratios were tested inside a constant volume chamber under various ambient temperatures so as to investigate the spray and combustion characteristics of the fuels. Applying the high speed imaging, a sudden drop in spray penetration was observed at ambient temperature of 800 K and 900 K for fuels with certain blending ratio, but not at 1000 K and 1200 K. When the spray penetration of the butanol-biodiesel-diesel blends was compared to that of the biodiesel-diesel blends under non-combusting environment, a sudden drop in spray penetration length was also observed at 1100 K. The results indicated that for the non-combusting case, the tip of the spray jet erupted into a plume sometime after injection for the butanol-biodiesel-diesel blend at an ambient temperature of 1100 K. Such phenomenon was not seen with the biodiesel-diesel blend, neither with the same fuel but at a lower ambient temperature of 900 K.

A very competitive alcohol for use in diesel engines is butanol. Butanol is of particular interest as a renewable bio-fuel, as it is less hydrophilic and it possesses higher heating value, higher cetane number, lower vapor pressure, and higher miscibility than ethanol or methanol. These properties make butanol preferable to ethanol or methanol for blending with conventional diesel or gasoline fuel. In this paper, the spray and combustion characteristics of pure n-butanol fuel was experimentally investigated in a constant volume combustion chamber. The ambient temperatures were set to 1000 K, and three different oxygen concentrations were set to 21%, 16%, and 10.5%. The results indicate that the penetration length reduces with the increase of ambient oxygen concentration. The combustion pressure and heat release rate demonstrate the auto-ignition delay becomes longer with decreasing of oxygen concentrations.

To face the challenges of fossil fuel shortage and air pollution problems, there is growing interest in the potential usage of alternative fuels such as bio-ethanol and bio-butanol in internal combustion engines. The literature shows that the acetone in the Acetone-Butanol-Ethanol (ABE) blends plays an important part in improving the combustion performance and emissions, owing to its higher volatility. In order to study the effects of acetone addition into commercial gasoline, this study focuses on the differences in combustion, performance and emission characteristics of a port-injection spark-ignition engine fueled with pure gasoline (G100), ethanol-containing gasoline (E30) and acetone-ethanol-gasoline blends (AE30 at A:E volumetric ratio of 3:1). The tests were conducted at 1200RPM with the default calibration (for gasoline), at 3 bar and 5 bar BMEP under various equivalence ratios.

Butanol, which is a renewable biofuel, has been regarded as a promising alternative fuel for internal combustion engines. When blended with diesel and applied to pilot ignited natural gas engines, butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency. However, high blend ratio of butanol is limited by its longer ignition delay caused by the higher latent heat and higher octane number, which restricts the improvement of emission characteristics. In this paper, the potential of increasing butanol blend ratio by adding hot exhaust gas recirculation (EGR) is investigated. 3D CFD model based on a detailed kinetic mechanism was built and validated by experimental results of natural gas engine ignited by diesel/butanol blends. The effects of hot EGR is then revealed by the simulation results of the combustion process, heat release traces and also the emissions under different diesel/butanol blend ratios.

Ignition location is one of the important factors that affect the thermal efficiency, exhaust emissions and knock sensitivity in premixed-charge ignition engines. However, the ignition initiation locations of pre-chamber generated turbulent jet ignition, which is a promising ignition enhancement method, are not clearly understood due to the complex physics behind it. Motivated by this, the ignition initiation location of a transient turbulent jet in a constant volume combustor is analyzed by the use of computational fluid dynamics (CFD) simulations. In the CFD simulations of this work, commercial codes KIVA-3 V release 2 and an in-house-developed chemical solver with a detailed mechanism for H2/air mixtures are used. Comparisons are performed between simulated and experimental ignition initiation locations, and they agree well with one another. A detailed parametric study of the influence of in-cylinder temperature on the ignition initiation location is also performed.

The formation of fuel film in the combustion cylinder affects the mixing process of the air and the fuel, and the process of the combustion propagation in engines. Some models of film evaporation have been developed to predict the evaporation behavior of the film, but rarely experimental results have been produced, especially when the temperature is high. In this study, the evaporation behavior of the film of different species of oil and their blends at different temperature are observed. The 45 μL films of isooctane, 1-propanol, 1-butanol, 1-pentanol, and their blends were placed on a quartz glass substrate in the closed temperature-controlled chamber. The shape change of the film during evaporation was monitored by a high-speed camera through the window of the chamber. First, the binary blends film of isooctane and one of the other three oils were evaporated at 30 °C, 50 °C, 70 °C and 90 °C.

An efficient multi-component fuel droplet vaporization model has been developed in this work using discrete approach. The precise modeling of droplet vaporization process is divided into two parts: vapor-phase and liquid-phase sub-models. Temporal evolution of flow inside the droplet is considered to describe the transient behavior introduced by the slow diffusion process. In order to account for the internal circulation motion, surface regression and finite diffusion without actually resolving the spatial governing equations within the liquid phase, a set of ordinary differential equations is applied to describe the evolution of the non-uniform distributions of universal diffusional variables, i.e. temperature and species mass fraction. The differences between the droplet surface and bulk mean states are modeled by constructing a quasi-1D frame; the effect of the internal circulations is taken into consideration by using the effective diffusivity rather than physical diffusivity.

This paper focuses on the spray and atomization characteristics of a Micro-Variable Circular-Orifice (MVCO) fuel injector coupled with a unique swirl adapter. Spray characteristics produced from this configuration, such as spray penetration length, spray velocity and the droplet size distribution were evaluated under different injection pressure and air inlet pressure. Diesel injection pressure ranges from 300 bar to 700 bar at a back pressure of 1bar while compressed air at pressures of 2 bar and 4 bar was supplied to the swirl adapter. High speed Mie scattering images were recorded to capture the spray evolution, as seen from both the front view and the bottom view. Phase Doppler Anemometry (PDA) measurements were conducted at different locations in the spray for the acquisition of droplet sizes and velocity distributions.

A numerical investigation of air-fuel mixing in gasoline direct-injection (GDI) engines is presented in this paper. The primary goal of this study is to demonstrate the importance of fuel representation. In the past studies, fuel has been usually modeled as a single component substance. However, most fuels are mixtures of hydrocarbons with diverse boiling points, resulting in mixture vaporization behavior substantially different from single-component behavior. This study presents a newly developed multicomponent vaporization model, which takes into account important mechanisms such as preferential vaporization, internal circulation, surface regression, and non-ideal behavior in high-pressure environments. A sheet spray atomization model was also used to calculate the disintegration of the liquid sheet and the breakup of the subsequent droplets. The results of a single-component fuel representation and a multicomponent fuel representation were compared.

Cavitation plays a significant role in the spray characteristics and the subsequent mixing and combustion process in engines. Cavitation has beneficial effects on the development of the fuel sprays by improving injection velocity and promoting primary break-up. On the other hand, intense pressure peaks induced by the vapor collapse may lead to erosion damage and severe degradation of the injector performance. In the present paper, the transient cavitating flow in the injector-like geometry was investigated using the modified turbulence model and cavitation criterion. A local density correction was used in the Reynolds-averaged Navier-Stokes turbulence model to reduce the turbulent viscosity, which facilitates the cavitation development. The turbulent stress was also considered in the cavitation inception stage. The modified model is capable of reproducing the cavitating flow with an affordable computational cost.

Flash boiling has drawn much attention recently for its ability to enhance spray atomization and vaporization, while providing better fuel/air mixing for gasoline direct injection engines. However, the behaviors of flash boiling spray with multi-component fuels have not been fully discovered. In this study, isooctane, ethanol and the mixtures of the two with three blend ratios were chosen as the fuels. Measurements were performed with constant fuel temperature while ambient pressures were varied to adjust the superheated degree. Macroscopic and microscopic characteristics of flash boiling spray were investigated using Diffused Back-Illumination (DBI) imaging and Phase Doppler Anemometry (PDA). Comparisons between flash boiling sprays with single component and binary fuel mixtures were performed to study the effect of fuel properties on spray structure as well as atomization and vaporization processes.

The spray structure and vaporization processes of flash-boiling sprays in a constant volume chamber under a wide range of superheated conditions were experimentally investigated by a high speed imaging technique. The Engine Combustion Network’s Spray G injector was used. Four fuels including gasoline, ethanol, and gasoline-ethanol blends E30 and E50 were investigated. Spray penetration length and spray width were correlated to the degree of the superheated degree, which is the ratio of the ambient pressure to saturated vapor pressure (pa/ps). It is found that parameter pa/ps is critical in describing the spray transformation under flash-boiling conditions. Three distinct stages namely the slight flash-boiling, the transition flash-boiling, and the flare flash-boiling are identified to describe the transformation of spray structures.

Inverted phi (ϕ)-sensitivity is a new approach of NOx reduction in compression-ignition (C.I.) engines. Previously, pure ethanol (E100) was selected as the preliminary test fuel in a single injection compression-ignition engine, and was shown to have good potential for low engine-out NOx emissions under low and medium load conditions due to its inverted ignition sequence. Under high load, however, the near-stoichiometric and non-homogeneous fuel/air distribution removes the effectiveness of the inverted ϕ-sensitivity. Therefore, it is desirable to recover the combustion sequence in the chamber such that the leaner region is burned before the near-stoichiometric region. When the combustion in near-stoichiometric region is inhibited, the temperature rise of that region is hindered and the formation of NOx is suppressed.

In the present study, we developed a reduced chemical reaction mechanism consisted of n-heptane and toluene as surrogate fuel species for diesel engine combustion simulation. The LLNL detailed chemical kinetic mechanism for n-heptane was chosen as the base mechanism. A multi-technique reduction methodology was applied, which included directed relation graph with error propagation and sensitivity analysis (DRGEPSA), non-essential reaction elimination, reaction pathway analysis, sensitivity analysis, and reaction rate adjustment. In a similar fashion, a reduced toluene mechanism was also developed. The reduced n-heptane and toluene mechanisms were then combined to form a diesel surrogate mechanism, which consisted of 158 species and 468 reactions. Extensive validations were conducted for the present mechanism with experimental ignition delay in shock tubes and laminar flame speeds under various pressures, temperatures and equivalence ratios related to engine conditions.